Introduction
Tomato paste is a key ingredient in the food industry, widely used in sauces, soups, and ready-to-eat meals. Its high concentration of sugars, acids, and moisture makes it particularly susceptible to microbial contamination and fermentation if not properly stored. Undesired fermentation alters the paste’s chemical composition, generating off-odors, gas production, and color changes—leading to product rejection and economic losses. Traditional quality control methods can be time-consuming or require destructive sampling. Electronic noses with temperature-modulated sensors provide a fast, non-invasive approach to detect changes in volatile organic compounds (VOCs), offering a practical solution for monitoring spoilage in tomato paste.
Methods
A digital electronic nose was assembled using commercial MOX gas sensors: BME688, ENS160, SGP40, and ZMOD4410. A colour sensor (AS7341) was also included. BME688 and ENS160 allowed the software to control the hotplate temperature, while SGP40 and ZMOD4410 were modulated by adjusting the heater voltage. Sensors were exposed to a triangular temperature/voltage waveform from 200 °C to 400 °C and 3.3 V to 0.5 V, respectively.
Four sealed 2.4 kg industrial tomato paste bags were obtained from local producers. Half of each bag served as a control, while the other half was mixed with 50 ml of water and stored at 25 °C to induce fermentation.
Results
The electronic nose showed distinct response curves when sweeping the sensor temperature. Fermented samples produced different VOC profiles compared to non-fermented ones, which was evident in the curve shapes for each sensor. These differences were consistent and repeatable across all sensor types.
Conclusions
This study confirms that an electronic nose with temperature-modulated MOX sensors can effectively distinguish between fresh and fermented tomato paste. The thermal response curves provide a unique fingerprint for each condition, supporting the use of this system for quality control and spoilage detection in tomato-based products.