Solvent-mediated reactivity of b-aminoalcohols against dialkyloxalate: synthesis of tetrasubstituted oxalamide and/ or morpholin-2,3-dione derivatives.

Maria Luisa Testa; Elena Zaballos-Garcia; Ramón Zaragozá

doi:10.3390/ecsoc-12-01198

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Tetrachlorosilane-A Versatile Reagent in Organic Synthesis

Solvent-mediated reactivity of b-aminoalcohols against dialkyloxalate: synthesis of tetrasubstituted oxalamide and/ or morpholin-2,3-dione derivatives.

Maria Luisa Testa

^{*

1},

Elena Zaballos-Garcia

²,

Ramón J. Zaragozá

¹ Istituto per lo Studio dei Materiali Nanostrutturati, CNR, via Ugo La Malfa 153, 90146 Palermo, Italy
² Departamento Química Orgánica, Universidad de Valencia, Av. Vicente Andres Estelles, E- 46100 Burjassot, Valencia, Spain
³ Departamento Química Orgánica, Universidad de Valencia, Dr. Moliner 50, E-46180 Burjassot, Valencia, Spain

Published: 30 November 2008 by MDPI in The 12th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-12-01198

Abstract: The reactivity of various b-aminoalcohols with diethyloxalate, in several reaction conditions, has been investigated. Lineal or cyclic derivatives were obtained depending on the nature of the solvent used and the starting material.

Keywords: tetrasubstituted oxalamide, morpholin-2,3-dione, theoretical calculations.

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Maria Luisa Testa

Elena Zaballos-Garcia

Ramón Zaragozá