Silicon Assisted Halogenation I: A Convenient Synthesis of β-chloroketones via Reaction of α,β-unsaturated ketones with Tetrachlorosilane-Phenol

Saad Elmorsy; Tarek Salama

doi:10.3390/ecsoc-13-00181

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SYNTHESIS OF HIGHLY FUNCTIONALIZED NON-RACEMIC CHIRAL ALKYL HALIDES USING KHARASCH ADDITION

Silicon Assisted Halogenation I: A Convenient Synthesis of β-chloroketones via Reaction of α,β-unsaturated ketones with Tetrachlorosilane-Phenol

Saad S. Elmorsy

Tarek A. Salama

¹ Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt
² Chemistry Department, Faculty of Education, Amran University, Amran, Yemen

Published: 31 October 2009 by MDPI in The 13th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-13-00181

Abstract: A combination of tetrachlorosilane (TCS) and phenol in dichloromethane was found to be an efficient reagent for hydrochlorination of α,β- unsaturated ketones to afford the corresponding β-chloroketones in good yield at ambient temperature.

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Saad Elmorsy

Tarek Salama