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SYNTHESIS OF DICOMPARTIMENTAL SCHIFF BASE LIGANDS. CRYSTAL STRUCTURE OF (N-N'-BIS(3- METHOXY or 3-ETHOXYSALICYLIDENE)-1,2-DIAMINE-2-METHYLPROPANE
, , , , * ,
1  Dpto. de Química Inorgánica. Facultad de Ciencias. Univ. de Santiago de Compostela. 27002 Lugo (Spain).

Abstract: The condensation of 3-methoxy or 3-ethoxy-2-hydroxybenzaldehyde and 1,2 diamine -2-methylpropane, to yield at the dianionic hexadentate Schiff base ligands H2 Ln (H2 L1 , H2 L2 respectively). The ligands have been characterised by elemental analysis, IR, 1H and 13C NMR spectroscopies and mass spectrometry (ES). The crystal structure of the two ligands was solved by X-ray crystallography, revealing its ability to bind metal centres.
Keywords: Supramolecular Chemistry / Dicompartimental Schiff bases / Hydrogen bonds / Manganese

 
 
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