Synthesis of Polymeric Luminophores Based on the Carbazole Derivative and Terbium (III) Complexes

Mateusz Galica; Dariusz Bogdał

doi:10.3390/ecsoc-16-01118

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Synthesis of Polymeric Luminophores Based on the Carbazole Derivative and Terbium (III) Complexes

Mateusz Galica

^*,

Dariusz Bogdał

¹ Cracow University of Technology, Faculty of Chemical Engineering and Technology

Published: 29 October 2012 by MDPI in The 16th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistry

https://doi.org/10.3390/ecsoc-16-01118

Abstract: This article focuses on the synthesis of a new polymeric phosphors containing Tb⁺³ ions as a potential material for next generation optoelectronics devices. We are presented the results on the synthesis and luminescence properties of copolymers containing: 2-(9-carbazolyl)ethyl methacrylate (CEM) and p-methacryloyloxybenzoic acid (pMBA) complexed with Tb(III). All copolymers have been characterized by HNMR, GPC, FTIR and UV-Vis. Solutions of the copolymers in THF or CHCl₃ have been examined for their photoluminescence properties. Finally, the possibility of using these materials in optoelectronics were compared to those already synthesized.

Keywords: carbazole, copolymers, luminescence, lanthanide

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Mateusz Galica

Dariusz Bogdał