Supramolecular polymer formed by ditopic cyclodextrin and ditopic adamantane derivatives

Alvaro Antelo; Mercedes Alcalde; Aida Jover; Francisco Meijide; Luciano Galantini; José Tato

doi:10.3390/ecsoc-12-01270

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Supramolecular polymer formed by ditopic cyclodextrin and ditopic adamantane derivatives

Alvaro Antelo

¹,

Mercedes Alvarez Alcalde

¹,

Aida Jover

¹,

Francisco Meijide

¹,

Luciano Galantini

²,

José Vázquez Tato

¹ Departamento de Química Física, Facultad de Ciencias, Universidad de Santiago de Compostela, Avda. Alfonso X El Sabio s/n, 27002 Lugo, Spain
² Dipartimento di Chimica, Research center SOFT-INFM-CNR, Università di Roma “La Sapienza”, P.le A. Moro 5, 00185 Roma, Italy

Published: 27 November 2008 by MDPI in The 12th International Electronic Conference on Synthetic Organic Chemistry session Supramolecular Chemistry

https://doi.org/10.3390/ecsoc-12-01270

Abstract: Novel host-guest supramolecular copolymers have been prepared from a ß-cyclodextrin (binded to ethylenediamintetraacetic acid, EDTA) dimer and a ditopic guest with two adamantyl groups bound to pyromellitic acid. Molecular weight and molecular size were determined from static and dynamic light scattering measurements (SLS and DLS, respectively). The analysis of results suggests that the supramolecular polymer adopts a shruck structure with an average molecular weight value of Mn =(1.51±0.02)×104 g·mol-1 (degree of polymerization equal to 5).

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Alvaro Antelo

Mercedes Alcalde

Aida Jover

Francisco Meijide

Luciano Galantini

José Tato