Synthesis of Polymeric Luminophores Based on the Carbazole Derivative and Terbium (III) Complexes

Mateusz Galica; Dariusz Bogdał

doi:10.3390/ecsoc-16-01160

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Synthesis of Polymeric Luminophores Based on the Carbazole Derivative and Terbium (III) Complexes

Mateusz Galica

^*,

Dariusz Bogdał

¹ Cracow University of Technology

Published: 30 October 2012 by MDPI in The 16th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistry

https://doi.org/10.3390/ecsoc-16-01160

Abstract: This article focuses on the synthesis of a new polymeric phosphors containing Tb+3 ions as a potential material for next generation optoelectronic devices. Here we are presented the results of the synthesis and luminescence properties of copolymers containing: 2-(9-carbazolyl)ethyl methacrylate (CEM) and p-methacryloyloxybenzoic acid (pMBA) complexed with Tb(III). All copolymers have been characterized by HNMR, GPC, FTIR and UV-Vis. Solutions of the copolymers in THF or CHCl3 have been examined for their photoluminescence properties. Finally, the possibility of using these materials in optoelectronics were compared to those already synthesized.

Keywords: carbazole, salicylic acid, copolymer, ion, luminesce, terbium complex

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Mateusz Galica

Dariusz Bogdał