Rapidly expanding and new applications of liquid crystal materials cover a wide range of technology products. A very incomplete list includes conventional and miniature high-resolution displays, AR/VR glasses, smart windows, dynamic lenses, tunable filters and retarders, electrically controlled sensors, reconfigurable antennas for wireless and space communications, and many other commercially available devices. The aforementioned devices are enabled by the collective reorientation of thermotropic molecular liquid crystals under the action of applied electric fields. The reorientation effects in liquid crystals can be altered by ionic contaminants typically present in mesogenic materials in small quantities. Therefore, information about ions in liquid crystals is very important because it allows for a proper selection of liquid crystal materials and uncompromised performance of liquid crystal devices. This information can be obtained by performing electrical measurements of liquid crystal materials. Measurements of basic electrical parameters (DC conductivity, charge mobility and ion density) are carried out using sandwich-like liquid crystal cells of finite thickness. Once a cell is filled with liquid crystal materials, interactions between ions and the cell substrates will result in the time dependence of the ion density and DC electrical conductivity until a steady state is reached. In this paper, we show how complementary information about ionic processes in liquid crystal cells can be obtained by analyzing their transient and steady state electrical properties.