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Syntheses of new azepane derivatives from monosaccharides
* 1 , 1 , 1 , 2
1  Departamento de Bioquímica, Biología Molecular y Química Orgánica, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga, Spain
2  Departamento de Química Orgánica, Facultad de Química, Universidad de Sevilla, 41012 Sevilla, Spain

Abstract: Synthetic routes to polyhydroxy azepanes from monosaccharides are described. The stereoselective formation of trans epoxyamides and regioselective epoxyde opening led to azido derivatives that could be transformed in azepanic structures. An anomalous result was obtained in the hydrogenation in MeOH with Pd/C of the azido derivative obtained from D-mannose
Keywords: n/a