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Reactivity of styrene derivatives: Nucleophilic addition versus 1,2-wittig rearrangement
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1  Departamento de Química Orgánica. Universidad de Santiago de Compostela. Facultad de Ciencias. Aptdo. 280, 27080 Lugo, Spain

Abstract: Wittig rearrangements have been studied for a long time, the [2,3]-rearrangement being the most widely studied, and there are many reports on its mechanistic and synthetic applications {1}. The corresponding [1,2]-rearrangement has been studied too, but has not been so widely used as a synthetic tool, remaining mainly as a competitive reaction that interferes with the other possible rearrangements.
Keywords: n/a