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Synthetic Active Site Analogues of Heme-Thiolate Proteins Catalysis and Identification of Elusive Intermediates
Published: 01 November 1998 by MDPI in The 2nd International Electronic Conference on Synthetic Organic Chemistry session Medicinal and Bioorganic Application of Organic Synthesis
Abstract: Intermediates of the catalytic cycles of chloroperoxidase and cytochrome P450cam are identified and characterized by means of synthetic enzyme models.
Keywords: chloroperoxidase · chlorination · cytochrome P450 . enzyme model · EPR-ENDOR-spectroscopy . heme-thiolate protein · iron porphyrin