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Titanocenes Catalyzed Diastereoselective Epoxidation of Allylic Alcohols.
Published: 01 November 1999 by MDPI in The 3rd International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
Abstract: Allylic alcohols undergo an efficient process of diastereoselective epoxidation by t-butyl hydroperoxide (TBHP) in n-hexane solution in the presence of catalytic amounts of mono- and dicyclopentadienyl titanium chlorides.