Asymmetric 1,3-Dipolar Cycloaddition Utilizing Tartaric Acid Ester as a Chiral Auxiliary

Yutaka Ukaji; Katsuhiko Inomata

doi:10.3390/ecsoc-4-01796

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Synthetic Applications of the Asymmetric Amino-Cope Rearrangement

Asymmetric 1,3-Dipolar Cycloaddition Utilizing Tartaric Acid Ester as a Chiral Auxiliary

Yutaka Ukaji

Katsuhiko Inomata

¹ Department of Chemical Science, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan

Published: 11 September 2000 by MDPI in The 4th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-4-01796

Abstract: In order to develop a practical method for the construction of chiral molecules, we have designed a novel chiral system possessing two metal centers utilizing tartaric acid esters. Based on this concept, catalytic asymmetric 1,3-dipolar cycloaddition of nitrile oxides and nitrones could be achieved with an high level of stereocontrol.

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Yutaka Ukaji

Katsuhiko Inomata