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Asymmetric 1,3-Dipolar Cycloaddition Utilizing Tartaric Acid Ester as a Chiral Auxiliary
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1  Department of Chemical Science, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan

Abstract: In order to develop a practical method for the construction of chiral molecules, we have designed a novel chiral system possessing two metal centers utilizing tartaric acid esters. Based on this concept, catalytic asymmetric 1,3-dipolar cycloaddition of nitrile oxides and nitrones could be achieved with an high level of stereocontrol.
Keywords: n/a