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METHYLENE INSERTION IN VINYLCUPRATES BEARING AN ALLYLIC SILYL GROUP
Published: 31 October 2009 by MDPI in The 13th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
Abstract: The silylcupration of allene has emerged as a useful tool for the synthesis of functionalized allylsilanes which have been used in the synthesis of different-sized carbocycles. We now described the preparation of allylsilane-allylcuprate intermediates by homologation reaction with iodomethylzinc iodide and their reaction with different electrophiles.