Please login first
Cohalogenation of Allyl- and Vinylsilanes using Polymer-bound Haloate(I)-Reagents
, , , , *
1  Institut fur Organische Chemie der Technischen Universitat Clausthal, Leibnizstrasse 6, D-38678 Clausthal-Zellerfeld, Germany

Abstract: Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OHs -form) vinyl silanes are converted into epoxysilanes in one pot.
Keywords: n/a