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Cohalogenation of Allyl- and Vinylsilanes using Polymer-bound Haloate(I)-Reagents
Published: 11 September 2000 by MDPI in The 4th International Electronic Conference on Synthetic Organic Chemistry session Solid Phase Chemistry and Combinatorial Synthesis
Abstract: Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OHs -form) vinyl silanes are converted into epoxysilanes in one pot.