A New Variant of the Baylis-Hillman Reaction for Solid Phase Organic Synthesis.

Ulrich Reiser; Johann Jauch

doi:10.3390/ecsoc-4-01888

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Hydroxy-(2-chlorophenyl)methyl Polystyrene Resin: Studies on the Immobilization and Cleavage of Acids and Alcohols

A New Variant of the Baylis-Hillman Reaction for Solid Phase Organic Synthesis.

Ulrich Reiser

Johann Jauch

¹ Institut für Organische Chemie und Biochemie, Technische Universität München, Lichtenbergstr. 4, D-85747 Garching, Germany.

Published: 11 September 2000 by MDPI in The 4th International Electronic Conference on Synthetic Organic Chemistry session Solid Phase Chemistry and Combinatorial Synthesis

https://doi.org/10.3390/ecsoc-4-01888

Abstract: A new variant of the Baylis-Hillman reaction based on lithium phenylselenide is adapted to Solid Phase Organic Synthesis (SPOS). Scope and limitations are studied using four polymer bound aldehydes.

Keywords: Solid phase synthesis, Baylis-Hillman reactions.

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Ulrich Reiser

Johann Jauch