Lignin electrolysis has emerged as an innovative and sustainable energy technology capable of producing “green hydrogen,” representing a more energy-efficient alternative to conventional water electrolysis [1–3]. Hydrogen, owing to its high energy density, clean combustion, and environmentally friendly nature, is considered a key energy vector to accelerate the transition away from fossil fuels [2,3]. However, traditional water electrolysis is often limited by high energy requirements and sluggish oxygen evolution kinetics, motivating the development of alternative strategies. In this study, lignin, a major component of biomass and an abundant renewable carbon source, was employed as an anodic feedstock to replace water oxidation. This approach not only reduces the overall energy demand but also simultaneously enables the valorization of lignin into value-added aromatic compounds.

To enhance catalytic efficiency, the catalysts were strategically engineered through structural tailoring to achieve a high surface area, abundant defects, and enriched oxygenated functional groups [4–6]. In particular, carbon-based catalysts with oxygenated acid sites demonstrated remarkable activity and stability in lignin electrolysis, facilitating efficient hydrogen generation at the cathode while promoting selective oxidation of lignin at the anode. As a result, this novel process yields pure hydrogen with reduced energy input and valuable organic by-products such as vanillin, thereby coupling green hydrogen production with biomass-waste valorization [3,8,10].

These findings highlight the dual benefit of lignin electrolysis: advancing renewable hydrogen production while providing a sustainable route for the circular use of biomass resources. This work underscores the potential of functional carbon-based catalysts as a versatile platform for clean energy and green chemistry applications.