Imine derivatives are an important class of compounds due their biological and optical properties making them suitable for several applications such as chemosensor, photochromic, and others.^1,2 In recent years the search for new colorimetric chemosensors for anions has been of great interest because of the role that ions play in chemical and biological processes.³  In this context and as part of an on-going research to develop efficient heterocyclic systems for photochromic and chemosensor applications⁴ we report in this communication the synthesis, the photophysical characterization and the chemosensor ability of pyrrolidene heterocyclic imines functionalized with aryl or naphthyl moieties.