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Synthesis of mono- and dinuclear cyclometallated compounds with palladium and platinum
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Published:
14 November 2020
by MDPI
in The 24th International Electronic Conference on Synthetic Organic Chemistry
session General Organic Synthesis
Abstract:
Cyclometallated compounds, particularly with palladium and platinum, have been extensively studied over the past years in part due to their applications as catalysts in cross-coupling reactions. They are also useful in medicinal chemistry, and quite a large number have luminescent properties.
Herein, the synthesis and characterization of novel palladium cyclometallated compounds and a study of their reactivity with a diphosphine ligand is discussed. Mono- and dinuclear compounds were prepared depending on phosphine ligand coordination.
Characterization has been carried by IR spectroscopy, 1H and 31P NMR spectroscopy.
Keywords: cyclometallation; palladium; platinum; thiosemicarbazone; diphosphine
