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The reactions of N,N'-diphenyldithiomalonamide with Michael acceptors
Published: 14 November 2020 by MDPI in The 24th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
N,N'-diphenyldithiomalonamide (dithiomalondianilide) smoothly reacts with various Michael acceptors to give either stable Michael adducts or products of their further heterocyclization. The structure of the products was confirmed by 2D NMR experiments and X-ray data. The mechanisms of the reactions are discussed.
Keywords: dithiomalondianilide, heterocyclization, 2-cyanoacrylates, Meldrum’s acid, Michael adducts
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