One-Pot Synthesis of syn-Epoxyalcohols from a,b-Unsaturated Ketones

Iris Dordevic; Bogdan Solaja

doi:10.3390/ecsoc-2-01685

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Polyalkoxy Nitrones as Chiral Building Blocks in Asymmetric Synthesis

One-Pot Synthesis of syn-Epoxyalcohols from a,b-Unsaturated Ketones

Iris Dordevic

¹,

Bogdan Solaja

^{*

2}

¹ Faculty of Veterinary Medicine, University of Belgrade, Belgrade
² Faculty of Chemistry, University of Belgrade, Studentski trg 16, P.O. Box 158, YU-11001 Belgrade

Published: 01 November 1998 by MDPI in The 2nd International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-2-01685

Abstract: a,b-Unsaturated ketones were transformed into syn-epoxyalcohols by sequential use of diisobutylaluminium hydride and tert-butylhydroperoxide

Keywords: Reduction of conjugated ketones, diisobutylaluminium hydride (DIBAH), syn-epoxidation, tertbutylhydroperoxide

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Iris Dordevic

Bogdan Solaja