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A divergent, versatile synthesis of d-aminoalkenes and related compounds from carbohydrates; selective formation of polyalkoxypiperidines and polyalkoxypyrans.
1 , 1 , 2 , * 1 , 1
1  Department of Chemistry, La Trobe University, Bundoora, Victoria 3083, Australia
2  Department of Applied Chemistry, RMIT, Plenty Rd, Bundoora, Victoria 3083, Australia

Abstract: A versatile synthesis of xylose derived d-aminoalkenes is presented. We have previously reported on the stereoselective synthesis of polyhydroxypiperidines.1 An extension to the methodology to incorporate more exotic Nsubstituted compounds was sought. This communication reports, in particular, the result of the completion of a synthetic sequence for the preparation of carbohydrate derived d-aminoalkenes.
Keywords: n/a

 
 
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