Total Synthesis of Monocyclofarnesane Norsesquiterpenoids Isolated from Mushroom Ingested by Beetle: Efficiency of Solid State Baeyer-Villiger Reaction

Hisahiro Hagiwara

doi:10.3390/ecsoc-4-01915

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Total Synthesis of Monocyclofarnesane Norsesquiterpenoids Isolated from Mushroom Ingested by Beetle: Efficiency of Solid State Baeyer-Villiger Reaction

Hisahiro Hagiwara

¹ Graduate School of Science and Technology, Niigata University, 8050, 2-nocho, Ikarashi, Niigata 950-2181, Japan

Published: 11 September 2000 by MDPI in The 4th International Electronic Conference on Synthetic Organic Chemistry session Bioorganic Chemistry and Natural Products

https://doi.org/10.3390/ecsoc-4-01915

Abstract: Nor- and bisnorsesquiterpenoids 1 and 2 have been synthesized starting from (S)-(+)-Wieland-Miescher ketone analogue 4 via solid state Baeyer-Villiger reaction as a key step.

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Hisahiro Hagiwara