Stereoselective Synthesis of 2-Amino-4-phosphono-4-pentenoic Acid Derivatives (AP4 Analogues)

M. Fernández; V. Ojea; M. Ruiz; S. Conde; A. Díaz; J. Quintela

doi:10.3390/ecsoc-1-02021

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Stereoselective Synthesis of 2-Amino-4-phosphono-4-pentenoic Acid Derivatives (AP4 Analogues)

M. C. Fernández

V. Ojea

M. Ruiz

S. Conde

A. Díaz

J. M. Quintela

¹ Departamento de Química Fundamental e Industrial. Facultade de Ciencias. Universidade da Coruña Campus A Zapateira s/n, A Coruña 15071. Spain.

Published: 01 September 1997 by MDPI in The 1st International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-1-02021

Abstract: a-Phoshono esters are widely employed substrates in olefin synthesis via Wadsworth-Emmons reaction.[1] Recently, Collignon and et al have described the organostannyl derivatives as useful intermediates in the synthesis of alkenylphosphonates.[2] In this communication we report our preliminary results on the stereoselective synthesis of amino acids containing alkenylphosphonates by using the a-triorganostannylated bislactim ether

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M. Fernández

V. Ojea

M. Ruiz

S. Conde

A. Díaz

J. Quintela