Co(I)-catalyzed [4&pi;+2&pi;] cycloaddition of 1,2-dienes to 1,3,5-cyclooctatriene in the synthesis of previously undescribed tricyclo[4.2.2.02.5]decenes

Gulnara Kadikova; Lilya Dzhemileva; Usein Dzhemilev

doi:10.3390/ecsoc-25-11633

Previous Article in event

Natural and synthetic dienoic and trienoic acids - an original method for the synthesis and antitumor activity.

Next Article in event

Azide-Alkyne Cycloaddition Catalyzed by a Glucose/Benedict Reagent System

Next Article in session

UNSATURATED FATTY ACID 10H2DA CONTENT IN SERBIAN ROYAL JELLY AND ITS EFFECTS ON MOTILITY OF COLORECTAL CARCINOMA CELL LINES

Co(I)-catalyzed [4π+2π] cycloaddition of 1,2-dienes to 1,3,5-cyclooctatriene in the synthesis of previously undescribed tricyclo[4.2.2.02.5]decenes

Gulnara Kadikova

^*,

Lilya Dzhemileva

Usein Dzhemilev

¹ Institute of Petrochemistry and Catalysis of RAS (IPC RAS)

Academic Editor: Julio A. Seijas

Published: 12 November 2021 by MDPI in The 25th International Electronic Conference on Synthetic Organic Chemistry session Bioorganic, Medicinal and Natural Products Chemistry

https://doi.org/10.3390/ecsoc-25-11633

Abstract:

The catalytic [4π+2π]-cycloaddition of mono- and disubstituted 1,2-dienes to 1,3,5-cyclooctatriene under the action of Co(acac)₂(dppe)/Zn/ZnI₂ was performed for the first time to give substituted tricyclo[4.2.2.02.5]dec-7-enes.

Keywords: [4π+2π]-cycloaddition; 1,3,5-cyclooctatriene; 1,2-dienes; tricyclo[4.2.2.02.5]dec-7-enes; cobalt(II) acetylacetonate; antitumor activity

View paper

47 Reads
0 Recommendations

Gulnara Kadikova

Lilya Dzhemileva

Usein Dzhemilev