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Sulfur-containing homo- and methanofullerenes, synthesis and study of tribological properties
Published: 14 November 2022 by MDPI in The 26th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
The data obtained by the authors in the field of carbon cluster chemistry, namely, the catalytic cycloaddition of sulfur-containing diazo compounds to C60-fullerene under the action of complex Pd-catalysts, are summarized. Cycloaddition reactions of diazoalkanes, diazoketones, diazothioates with C60- fullerene, catalyzed by Pd(acac)2-PPh3-Et3Al, with selective formation of new sulfur-containing methano- and homo-, and pyrazolinofullerenes, promising as modern nanosized additives to oils for highly loaded mechanisms.
Keywords: fullerenes, diazo compounds, methanofullerenes, homofullerenes, metal complex catalysis, tribology, additives
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