Sulfur-containing homo- and methanofullerenes, synthesis and study of tribological properties

Artur Khuzin; Airat Tuktarov; Usein Dzhemilev

doi:10.3390/ecsoc-26-13537

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Synthesis of 6-(4-Chlorophenyl)-N-aryl-4-(trichloromethyl)-4H-1,3,5-oxadiazin-2-amines: Comparative Evaluation of Dehydrosulfurization Methods of Starting 4-Chloro-N-(2,2,2 -trichloro-1-(3-arylthioureido)ethyl)benzamides.

Sulfur-containing homo- and methanofullerenes, synthesis and study of tribological properties

Artur A Khuzin

Airat R. Tuktarov

^*,

Usein M. Dzhemilev

¹ Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences

Academic Editor: Julio A. Seijas

Published: 14 November 2022 by MDPI in The 26th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-26-13537

Abstract:

The data obtained by the authors in the field of carbon cluster chemistry, namely, the catalytic cycloaddition of sulfur-containing diazo compounds to C₆₀-fullerene under the action of complex Pd-catalysts, are summarized. Cycloaddition reactions of diazoalkanes, diazoketones, diazothioates with C₆₀- fullerene, catalyzed by Pd(acac)₂-PPh₃-Et₃Al, with selective formation of new sulfur-containing methano- and homo-, and pyrazolinofullerenes, promising as modern nanosized additives to oils for highly loaded mechanisms.

Keywords: fullerenes, diazo compounds, methanofullerenes, homofullerenes, metal complex catalysis, tribology, additives

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Artur Khuzin

Airat Tuktarov

Usein Dzhemilev