Synthesis of 1-vinyl isoquinolines and isoindolines by cyclization of acyliminium ions derived from allenamides

A. Navarro-Vázquez; D. Rodríguez; M. Martínez-Esperón; A. García A. García; C. Saá; D. Domínguez

doi:10.3390/ecsoc-10-01404

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Synthesis of 1-vinyl isoquinolines and isoindolines by cyclization of acyliminium ions derived from allenamides

A. Navarro-Vázquez

D. Rodríguez

M. F. Martínez-Esperón

A. García A. García

^*,

C. Saá

D. Domínguez

¹ Departamento de Química Orgánica y Unidad Asociada al CSIC, Facultad de Química, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain

Published: 30 November 2006 by MDPI in The 10th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-10-01404

Abstract: A new approach to 1-vinyl isoquinolines and isoindolines using as the key step the acid catalyzed cyclization of allenamides via an acyliminium ion intermediate has been achieved.

Keywords: n/a

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A. Navarro-Vázquez

D. Rodríguez

M. Martínez-Esperón

A. García A. García

C. Saá

D. Domínguez