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Behaviour of 2-nitroheterocycles in Cycloaddition Reactions
Published:
01 November 2005
by MDPI
in The 9th International Electronic Conference on Synthetic Organic Chemistry
session General Organic Synthesis
Abstract: Five membered aromatic 2-nitroheterocycles are studied in Diels-Alder reactions. 2-nitrofuran and 1-tosil-2-nitropyrrole yielded normal cycloadducts with isoprene and Rawal´s diene. Formation of pyrrolyl-derivatives are observed in reactions of 2-nitrothiophene and 2-nitroselenophene with isoprene.
Keywords: 2-nitroheterocycles, dienophiles, Diels-Alder2-nitroheterocycles; dienophiles; Diels-Alder