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Use of a new hydrophilic phosphonic phosphines (DPPA). Heck Reaction in Aqueous Medium under Microwave Irradiation.
Published: 01 November 1998 by MDPI in The 2nd International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
Abstract: The Heck reaction is efficiently and rapidly obtained by a palladium-catalysed reaction in water performed in a Teflon autoclave under microwave irradiation with a commercial microwave oven. Water soluble phosphine-ligand catalysts and phase transfer catalysis conditions are used.
Keywords: Heck reaction, Microwaves, Phase-transfer catalysis, Water-soluble phosphine, LogP, DPPA