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Use of a new hydrophilic phosphonic phosphines (DPPA). Heck Reaction in Aqueous Medium under Microwave Irradiation.
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1  Ecole Nationale Superieure d' Ingenieurs de Caen, I.S.M.R.A., Universite de Caen UMR CNRS 6507, 6 Boulevard du Marechal Juin F-14050 Caen Cedex, France

Abstract: The Heck reaction is efficiently and rapidly obtained by a palladium-catalysed reaction in water performed in a Teflon autoclave under microwave irradiation with a commercial microwave oven. Water soluble phosphine-ligand catalysts and phase transfer catalysis conditions are used.
Keywords: Heck reaction, Microwaves, Phase-transfer catalysis, Water-soluble phosphine, LogP, DPPA