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Synthesis of Glycosyl Phosphoramidates: Novel Isosteric Analogs of Glycosyl Phosphates
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1  Indian Institute of Technology Madras, Chennai-600 036, India

Abstract: Several glycosyl phosphoramidates, which are novel isosteric analogs of glycosyl phosphates, were synthesized in four steps starting from the free sugars, the key step being the Staudinger reaction of fully acetylated b -D-glycosyl azide with trimethyl phosphite.
Keywords: Glycosyl phosphoramidates, Isosteric analogs, Staudinger reaction.