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Impact of TiO2 on Glass–Ceramic Photocatalysis
* 1 , * 1 , * 2 , * 3 , * 1 , * 1
1  Materials Sciences and Process Optimization Laboratory, Faculty of Sciences Semlalia, University Cadi Ayyad, 4000 Marrakech, Morocco
2  Laboratory of Chemical Processes and Applied Materials, Faculty Poly Disciplinary, University Sultan Moulay Slimane, 23030 Beni Mellal, Morocco/ Materials Sciences and Process Optimization Laboratory, Faculty of Sciences Semlalia, University Cadi Ayyad, 4
3  Laboratory Analytical and Molecular Chemistry, Faculty Poly Disciplinary, University Cadi Ayyad, 46000 Safi, Morocco
Academic Editor: Jesus Sanmartín-Matalobos

Abstract:

Glass ceramics, formed through the meticulous control of glass crystallization, have become indispensable in modern life owing to their multifaceted utility. Their shape and size adaptability, exceptional stability across various conditions, ease of fabrication, and consistent performance render them pivotal in addressing pressing environmental concerns. These qualities position them as potential solutions to urgent challenges.

Phosphate glasses, widely utilized, offer fertile ground for exploration in photocatalysis with the integration of TiO2. In our study, glasses with varying TiO2 concentrations (0%, 2.5%, 5%, 7.5%, and 10%) were melted at 1200°C. This process induces the transition from an amorphous state into a glass ceramic state within a temperature span encompassing both melting and crystallization. Analysis of thermal, structural, and morphological attributes reveals that augmenting TiO2 content in phosphate glass amplifies its photocatalytic efficacy, resulting in the accelerated degradation of organic pollutants under light exposure. These findings underscore the pivotal role of TiO2 in enhancing the environmental performance of glass, thus paving the way for sustainable and innovative advancements.

In summary, the evolution of glass ceramics from controlled crystallization techniques heralds a new era in addressing environmental challenges. Incorporating TiO2 into phosphate glasses is promising for advancing photocatalytic applications, offering a pathway to mitigate environmental degradation. As research progresses, these materials are poised to play a pivotal role in fostering sustainability and innovation.

Keywords: Phosphate glasses, Glass ceramics, Recrystallization, Photocatalysis, TiO2

 
 
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