Novel Synthesis of a,b-Diketoesters from a,a-Dioxo-type Oximes or Oxime Ethers via Zinc-Induced Deoximation

Ilhyong Ryu; Hiroki Kuriyama; Hironari Miyazato; Mitsuo Komatsu; Joo-Yong Yoon; Sunggak Kim

doi:10.3390/ecsoc-4-01829

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Novel Synthesis of a,b-Diketoesters from a,a-Dioxo-type Oximes or Oxime Ethers via Zinc-Induced Deoximation

Ilhyong Ryu

^*,

Hiroki Kuriyama

¹,

Hironari Miyazato

¹,

Mitsuo Komatsu

¹,

Joo-Yong Yoon

²,

Sunggak Kim

^{*

2}

¹ Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka, 565-0871, Japan
² Center for Molecular Design and Synthesis, Department of Chemistry, Korea Advanced Institute of Science and Technology, Taejon 305-701, Korea

Published: 11 September 2000 by MDPI in The 4th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-4-01829

Abstract: a,b-Diketoesters can be conveniently prepared from the corresponding a,a’-dioxo-type oximes or oxime ethers using a zinc/AcOH reduction system.

Keywords: n/a

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