Contribution to the Stereoselective Synthesis of (3'S)-Isothiocyanato-3'-C-vinyl-3'-deoxyuridine and Its Derivatives

M. Martinková; M. Šoteková; J. Gonda; M. Budĕšínský; I. Císařová

doi:10.3390/ecsoc-8-01954

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Contribution to the Stereoselective Synthesis of (3'S)-Isothiocyanato-3'-C-vinyl-3'-deoxyuridine and Its Derivatives

M. Martinková

^{*

1},

M. Šoteková

¹,

J. Gonda

¹,

M. Budĕšínský

^{*

2},

I. Císařová

^{*

3}

¹ Department of Organic Chemistry, Institute of Chemical Sciences, P. J. Šafárik University, SK-041 67 Košice, Slovakia
² Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, CZ-166 10 Prague, Czech Republic
³ Department of Inorganic Chemistry, Faculty of Sciences of the Charles University, CZ-128 40 Prague, Czech Republic

Published: 01 November 2004 by MDPI in The 8th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-8-01954

Abstract: A stereoselective synthesis of the (3¢S)-isothiocyanato-3¢-C-vinyl-3¢-deoxyuridine via (3,3)-sigmatropic rearrangement of allylic thiocyanate derived from protected uridine was investigated.

Keywords: n/a

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M. Martinková

M. Šoteková

J. Gonda

M. Budĕšínský

I. Císařová