Essential oils (EOs) can be obtained from the waste products of lemon production, and are highly valued by the pharmaceutical and food industries. It should be noted that they are very susceptible to deterioration reactions, which is why spray encapsulation is frequently used.

The objective of this work was to obtain and characterize the EOs obtained by the hydrodistillation of the epicarp of fresh lemons (Citrus limon L.) and to combine them with different matrices as a tool to improve the quality and physical stability of dehydrated systems. Maltodextrin, commercial saccharose and starch were used to prepare two emulsions containing EOs. The powders were obtained by spray drying. The constant operational conditions were as follows: inlet and outlet air temperature at 98 and 68 °C, respectively, flow rate 8 mL/min, air pressure 3.2 bar, and nozzle diameter 1.5 mm.

The physicochemical characterization of each EO was carried out by pycnometry (20ºC) and using the refractive index (20ºC).

The aroma composition of each EO was determined by GC–MS and FT-IR. The inclusion complexes were characterized by differential scanning calorimetry (DSC) and by their sorption properties.

The D’Arcy–Watt and GAB models were used to describe the data obtained. Both models were complementary for the best interpretation of the water sorption mechanisms and the structure of the wall material.

These data are necessary for the sustainable use of subproducts.