In the present scenario, one of the most important ways to minimize waste and protect the ecological balance is to transform agricultural by-products into profitable commodities. A considerable quantity of apricot kernels produced from canning industries remains largely underutilized and undervalued. An initiative to advance sustainable development goals was undertaken by harnessing these apricot kernels. In this study, the impact of various film-forming matrices on the quality attributes of composite packaging films composed of apricot kernel protein isolate (AKPI), corn starch (CS) and mint oil (MO) at varied ratios of 100:0:0, 90:10:1, 80:20:1; 70:30:1, 60:40:1, and 50:50:1 was explored. The study outcomes revealed that each film-forming solution produced self-supporting and easily peelable packaging films. A composite film comprising 50% AKPI, 50% CS, and 10% MO (P₅₀C₅₀O₁) was observed to have favorable properties among the explored formulations. The P₅₀C₅₀O₁ film showed 1.96-fold superior thermal stability, 1.35-fold higher tensile strength, and a 1.65-fold reduction in water vapor permeability than the AKPI film, indicating a smaller presence of moisture and the enhanced tortuosity of the vapor diffusion pathway. Microstructure analysis exhibited smoother and more uniformly entrapped MO in P₅₀C₅₀O₁ film, while X-ray diffraction patterns indicated a rise in crystallinity and improved interactions between molecules. Compared to AKPI film, P₅₀C₅₀O₁ composite film showed the highest color difference of 6.19, suggesting a reduction in the purity of the dark greenish color. The study outcomes thus demonstrate a novel approach to fabricating composite packaging films by utilizing agro-food waste (apricot kernels), providing a sustainable solution for utilizing by-products from apricot processing industries.