Introduction: The transparency and aesthetics of clear aligners are critical factors that influence patient satisfaction and psychological and social well-being. Based on our previous research on the chemical–physical characterization of polyethylene terephthalate glycol (PET-G) aligners exposed to staining agents and cleaning solutions, this study aimed to evaluate the color stability of PET-G after prolonged exposure to everyday substances, potentially due to chemical interactions affecting aligner transparency.
Methods: Twenty-five sheets of PET-G and a truncated pyramid-shaped thermoforming mold were used to obtain flat samples (n = 220). These samples were immersed in various substances (coffee, tea, Coca-Cola, red wine, colloidal silver-based disinfectant, nicotine, artificial saliva, cigarette smoke, and three saliva solutions mixed with plain, coffee, and nicotine). Immersion times of 10 (n = 110) and 15 days (n = 110) were randomized. L*a*b* parameters were measured before and after immersion for colorimetric assessment, and the total color change (ΔE) was calculated for evaluation. Statistical analysis included nonparametric tests, with significance set at P < 0.05.
Results: Significant colorimetric changes were detected in PET-G samples exposed to acidic or polyphenol-rich substances, suggesting that chemical interactions may drive discoloration. Pairwise comparisons highlighted significant differences between ΔE values for groups exposed to different substances, particularly coffee, tea, and Coca-Cola, at both immersion durations. In addition, highly significant colorimetric changes were demonstrated between the two times, particularly for samples exposed to coffee, tea, and Coca-Cola. Clinical evaluations revealed slight to noticeable color changes, with Coca-Cola causing more pronounced changes, especially after 15 days.
Conclusions: Prolonged exposure to certain substances significantly affects PET-G's color stability, likely due to chemical adherence and degradation mechanisms, which has important psychological and social implications for patients undergoing orthodontic treatment. This study underscores the need for proactive strategies to maintain aligner transparency and enhance patient satisfaction.