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A Model Based Analysis of Direct Methanol Production from CO2 and Renewable Hydrogen.
* 1 , 1 , 2 , 2 , 2
1  Department of Automation and Digital Control, Tashkent Institute of Chemical Technology, Tashkent, Uzbekistan
2  Department of Engineering Technologies, Shahrisabz Branch of Tashkent Chemical-Technological Institute, Shahrisabz, Uzbekistan
Academic Editor: Grazia Leonzio

Abstract:

Methanol synthesis from CO2 is a key strategy for carbon capture and utilization, offering a viable solution to mitigate climate change. Direct synthesis of methanol not only reduces greenhouse gases but also produces valuable chemicals for industrial applications. The aim of this study is to model and optimize the methanol synthesis process from CO2, focusing on maximizing methanol yield while minimizing CO2 content in the product stream. In this work, a detailed methanol synthesis process simulation was developed using the Soave-Redlich-Kwong equation of state in the Aspen Plus commercial software environment. Pure CO2 stream which comes out of post-combustion carbon capture process and renewable hydrogen stream are used. The results are compared with open literature sources. Apart from that, a sensitivity analysis was employed to evaluate the effects of pressure, temperature, and recirculation fraction on process efficiency. The results showed that the highest methanol yield of 76,838 kg/h was obtained at 80 bar, 276°C, and a recirculation fraction of 0.9. The lowest CO2 content in the final product (73 kg/h) occurred at 80 bar, 220°C, and a recirculation fraction of 0.6. These findings demonstrate the trade-off between maximizing methanol output and reducing unreacted CO2. In conclusion, optimal operating conditions for both high yield and low CO2 content were identified, providing a foundation for further process refinement. Future work will involve developing a more complex multi-reactor model and conducting economic assessments for large-scale industrial implementation.

Keywords: CO2 utilization; methanol synthesis; methanol yield; modelling; sensitivity analysis
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