Different Bridging Preferences of Zinc and Palladium in Dimeric Complexes of a Ligand Based on 2-Tosylaminomethylaniline

Jesús Sanmartín-Matalobos; Cristina Portela-García; Matilde Fondo; Ana García-Deibe

doi:10.3390/ecsoc-18-e005

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Different Bridging Preferences of Zinc and Palladium in Dimeric Complexes of a Ligand Based on 2-Tosylaminomethylaniline

Jesús Sanmartín-Matalobos

^*,

Cristina Portela-García

Matilde Fondo

Ana García-Deibe

¹ Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain

Published: 31 October 2014 by MDPI in The 18th International Electronic Conference on Synthetic Organic Chemistry session Computational Chemistry

https://doi.org/10.3390/ecsoc-18-e005

Abstract: We report here the formation of dimeric palladium(II) and zinc(II) complexes of a ligand (H2L) derived from the condensation of 2 tosylaminomethylaniline and 2,3-dihydroxybenzaldehyde.The structures in solution of the corresponding palladium(II) and zinc(II) complexes could be deduced from NMR studies. With the aim of establishing an energy-structure relationship between the two possible linkage isomers (μ-O bridged and μ-N bridged), some theoretical energy calculations have been performed.

Keywords: Linkage isomerism; dimeric complexes; sulfonamido bridge; phenoxo bridge

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Jesús Sanmartín-Matalobos

Cristina Portela-García

Matilde Fondo

Ana García-Deibe