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Polymerisation Kinetics Photoinduced by Derivatives of Para-Nitroaniline in the Presence of N,N-Dipropylaniline
Published: 31 October 2014 by MDPI in The 18th International Electronic Conference on Synthetic Organic Chemistry session Polymer and Supramolecular Chemistry
Abstract: We investigated a possibility of the para-nitroaniline applying as a photopolymerization initiator. To carry out photopolymerization a system consisting of para-nitroaniline and N,N-Dipropylaniline was irradiated with UV light with a wavelength at 365 nm. When adding monomer in this system there was observed polymer formation. It is important to note that these results were not detected using either the nitro compound or the amine monomer as well as to the system without the monomer. The paper shows the kinetics of polymerization at low conversion with different ratios of amine and nitro compounds.
Keywords: Photopolymerization initiator; para-nitroaniline; N,N-Dipropylaniline