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Superbasic system CsOH/DMSO as a reagent for a fast one-step synthesis of symmetrical dialkyl trithiocarbonates
Published:
30 October 2015
by MDPI
in The 19th International Electronic Conference on Synthetic Organic Chemistry
session General Organic Synthesis
Abstract:
Symmetrical dialkyl trithiocarbonates were readily synthesized in excellent yields by one-step reaction
of carbon disulfide and various alkyl halides under mild reaction conditions in the presence of
cesium hydroxide as a super basic system. This method provides a synthesis of symmetrical dialkyl
trithiocarbonates in short reaction times without the use of highly toxic starting materials.
Comments on this paper
Andrei Potapov
3 November 2015
other hydroxides
Hello,
thank you for a nice contribution.
I was just wondering if other hydroxides (especially KOH) would work in this reaction. Have you tried that?
Andrei
thank you for a nice contribution.
I was just wondering if other hydroxides (especially KOH) would work in this reaction. Have you tried that?
Andrei
