Facile access to amidoethyl-p-benzoquinones

Mariam Al Azani; Nuha al Soom; Jesus Iniesta; Thies Thiemann; Thies Thiemann

doi:10.3390/ecsoc-19-a035

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Facile access to amidoethyl-p-benzoquinones

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¹ Department of Chemistry, United Arab Emirates University, Al Ain, UAE
² Institute of Electrochemistry and Physical Chemistry Department, University of Alicante

Published: 30 October 2015 by MDPI in The 19th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-19-a035

Abstract: Amidoethyl-p-benzoquinones are easily accessible from 2,5-dimethoxybenzaldehyde. A one-step Wittig-hydrolysis reaction is followed by an amidation of the produced 2,5-dimethoxycinnamic acid. Hydrogenation and oxidative demethylation complete the sequence to the respective amidoethyl-p-benzoquinones. The spectroscopic data of the products is discussed.

Keywords: p-benzoquinones, oxidative demethylation, amides

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