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1 , 1 , 2 , 3 , 3 , * 2
1  Instituto de Química Médica, Centro de Química Orgánica Manuel Lora-Tamayo, CSIC, Juan de la Cierva 3, E-28006 Madrid, Spain
2  aDepartamento de Química Orgánica y Bio-Orgánica, Facultad de Ciencias, UNED, Paseo de Senda del Rey 9, E-28040 Madrid, Spain Tel.: + 34913987327; fax: + 34913988372
3  Department of Organic Chemistry, Institute of Organic Chemistry, Catalysis and Petrochemistry, Faculty of Chemical and Food Technology, Slovak University of Technology,Radlinského street 9, SK-81237 Bratislava, Slovak Republic

Abstract: The 1H, 13C and 15N NMR spectra, both in solution and in the solid state, of five 1,2-phenylenediamines have been recorded. Assignment of all the signals has been achieved and chemical shifts and coupling constants determined. When necessary homo- and heteronuclear 2D NMR experiments have been performed.
Keywords: aromatic amines, 1H NMR, 13C NMR, 15N NMR