Synthesis of a novel porphyrin-based metal organic framework (Co-Por MOF)

Leila Tayebi; Rahmatollah Rahimi; Mahboubeh Rabbani

doi:10.3390/ecsoc-23-06483

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Application of a terephthalate and pyrazine-based MOF in Cr adsorption

Synthesis of a novel porphyrin-based metal organic framework (Co-Por MOF)

Leila Tayebi

¹,

Rahmatollah Rahimi

^{*

1},

Mahboubeh Rabbani

¹ Department of Chemistry, Iran University of Science and Technology
² Department of chemistry, Iran University of Science and Technology, Tehran, Iran

Published: 14 November 2019 by MDPI in The 23rd International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-23-06483

Abstract:

In this study, a novel porphyrin-based metal–organic framework (Co-Por MOF) has been successfully synthesized by a simple one-step solvothermal method. we report a metal organic framework based on covalent interaction of an organic linker, 5,10,15,20-tetrakis(4-carboxyphenyl) porphyrin (TCPP) with cobalt clusters. The properties of this material were analyzed by powder X-ray diffraction (XRD), ultraviolet visible adsorption spectroscopy (UV–Vis), fourier-transform infrared spectroscopy (FTIR), differential reflectance spectroscopy (DRS).

Keywords: Porphyrin-based metal–organic framework, Co-Por MOF, Simple one-step solvothermal method, TCPP.

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Leila Tayebi

Rahmatollah Rahimi

Mahboubeh Rabbani