The A0→L10 phase transformation, which appears in red gold alloys with compositions close to Au-Cu, is well known as diffusive. However, a shape memory effect has been reported in these alloys, which must involve variant selection during a displacive transformation. Therefore, in this work, the variant selection is studied by EBSD in a polycrystalline red gold alloy heat treated under 4-point bending. For the first time, the L10 domains could be identified by EBSD despite their c/a ratio close to unity and their nanometric scale. The orientation relationship between parent and daughter phases was determined and the mechanical work of the variant formation calculated from both the lattice distortion and the experimental orientations. The maximal work criterion, initially introduced for variant selection in martensitic transformations, was applied on large-scale areas with statistical data and it provided quantitative results on the degree of variant selection in both tension and compression.
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EBSD study of variant selection in red gold alloys during phase transformation under four point bending
Published:
06 November 2020
by MDPI
in The 2nd International Online Conference on Crystals
session Phase Transformations in Crystalline Materials
Abstract:
Keywords: EBSD, Variant selection, Red gold alloys