Hexa-substituted hybrid C60 derivatives with norbornadiene fragments: synthesis and structure

Arslan Akhmetov; Zarema Sadretdinova; Arthur Tulyabaev; Leonard Khalilov

doi:10.3390/ecsoc-27-16104

Previous Article in event

A new synthesis of poly heterocyclic compounds containing nitrogen and boron atoms

Next Article in event

Study of the influence of the solvent on the crystal structure of an ethyl-substituted bisthiosemicarbazone ligand

Hexa-substituted hybrid C60 derivatives with norbornadiene fragments: synthesis and structure

Arslan Akhmetov

^*,

Zarema R Sadretdinova

Arthur Tulyabaev

Leonard Khalilov

¹ 450075 Institute of petrochemistry and catalysis of RAS Pr. Oktyabrya 141, Ufa, Russia

Academic Editor: Julio A. Seijas

Published: 15 November 2023 by MDPI in The 27th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-27-16104

Abstract:

New hybrid fullerene C60 derivatives with five norbornadiene fragments bound to a fullerene core by several methylene groups were synthesized for the first time. Subsequent photoirradiation of these C60 fullerene derivatives leads to only partial (up to 20%) opening of double bonds in norbornadiene fragments to form quadricyclane substituents. It is assumed that the resulting C60 fullerene derivatives can be the basis to create high-energy materials.

Keywords: C60 fullerene, high-energy materials, quadricyclane, norbornadiene

View paper

0 Reads
0 Recommendations