Synthesis and Characterization of a New Triptycene-Based Tripod

Jesús Sanmartín-Matalobos; Ana García-Deibe; Matilde Fondo; José Pérez-Lustres; Sourav Sourav Bhowmick; Neeladri Das

doi:10.3390/ecsoc-18-a007

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Synthesis and Characterization of a New Triptycene-Based Tripod

Jesús Sanmartín-Matalobos

^{*

1},

Ana García-Deibe

¹,

Matilde Fondo

¹,

José Luis Pérez-Lustres

²,

Sourav Sourav Bhowmick

³,

Neeladri Das

¹ Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain
² Centro Singular de Investigacion en Química Biológica y Materiales Moleculares (CIQUS), Universidad de Santiago de Compostela, Jenaro de la Fuente s/n, 15782 Santiago de Compostela, Spain.
³ Department of Chemistry. Indian Institute of Technology (IIT) of Patna. Patna, Bihar, 800013. INDIA

Published: 31 October 2014 by MDPI in The 18th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-18-a007

Abstract: Herein, we report an efficient and facile synthesis of a new triptycene based tripodal ligand containing both imine functionality and phenolic pendant arms. This tripodal unit is a potential building block for constructing novel supramolecular architectures. The newly synthesized 2,6,14-triaminotriptycene derivative, which was characterized by FT-IR, UV−Vis absorption, mass and NMR spectroscopic techniques has interesting properties such as high solubility in common organic solvents and fluorescence emission in THF solution (λ = 550 nm).

Keywords: Fluorescence emission; Triptycene derivatives; Schiff bases; Tripods

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Jesús Sanmartín-Matalobos

Ana García-Deibe

Matilde Fondo

José Pérez-Lustres

Sourav Sourav Bhowmick

Neeladri Das