Efficient Catalytic Oxidation of Cyclohexane by Metalloporphyrins Encapsulated Mesoporous MCM-48

Mansoor Anbia; Rahmatollah Rahimi; Nafiseh RahmaniKhalili

doi:10.3390/ecsoc-14-00496

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Efficient Catalytic Oxidation of Cyclohexane by Metalloporphyrins Encapsulated Mesoporous MCM-48

Mansoor Anbia

Rahmatollah Rahimi

Nafiseh RahmaniKhalili

¹ Department of chemistry, Iran University Of Science & Technology, Tehran 16846-13114, Iran

Published: 05 November 2010 by MDPI in The 14th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-14-00496

Abstract: Catalytic oxidation of cyclohexane by two metalloporphyrins {manganese and iron 5, 10, 15, 20-meso-tetrakis-(p-chlorophenyl) porhyrin}immobilized in mesoporous MCM-48 with TBHP in acetonitril was investigated. It was found that immobilization significantly enhances catalytic activity as compared to the homogenous system.

Keywords: cyclohexane oxidation; metalloporphyrins; MCM-48

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Mansoor Anbia

Rahmatollah Rahimi

Nafiseh RahmaniKhalili