Synthesis of silver ion conducting polymer composites and its optical, electrical and morphological properties were conducted. In the study various amounts of titanium dioxide (TiO₂) was added to the chitosan:silver nitrate (CS:AgNt) system. The appearance of SPR peak for CS:AgNt system and CS:AgNt doped with 1 wt.% TiO₂ and disappearance of SPR peak for the system incorporated with 5 wt.% TiO₂ reveals the formation of silver particle from nano scales to bulk metallic sizes. The optical microscope images reveal the formation of silver particles with bulk metallic sizes at wt.% TiO₂ filler . The SEM images show silver particles with small sizes for CS:AgNt and CS:AgNt incorporated with 1 wt.% TiO₂. To make sure the reduction process of silver ions to metallic silver particles the impedance spectroscopy has been carried out. The decrease of dielectric constant and DC conductivity at high TiO₂ concentration was correlated with the results of UV-vis and morphological achievments. Shifting of tanδ loss peak towards the lower frequency side at 5 wt.% TiO₂ is an evident for the decrease in conductivity. The results of the present work reveals that silver ion conducting polymer electrolytes mediated by TiO₂ filler are not suitable for electrochemical device application. Distinct peaks become visible in Mi spectra whereas no peaks can be seen in dielectric loss spectra.