Synthesis of some polycyclic aryls by haloaryl coupling with zinc dust – (trialkyl)ammonium formate reagent

Vladimir Bulavka

doi:10.3390/ecsoc-10-01408

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Unexpected result of reaction of b-halogen-a-tosyl-substituted ureas with b-oxoesters and 1,3-diketones. Synthesis of 3-acyl-substituted 5-ureido-4,5-dihydrofurans

Synthesis of some polycyclic aryls by haloaryl coupling with zinc dust – (trialkyl)ammonium formate reagent

Vladimir N. Bulavka

¹ Slavich Company, Mendeleev sq. 2, Pereslavl-Zalesskiy, Yaroslavl region, 152020, Russian Federation

Published: 30 November 2006 by MDPI in The 10th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-10-01408

Abstract: The method for coupling of haloaryls to polycyclic aryls with zinc dust and (trialkyl)ammonium formate in an inert atmosphere was extended for polycyclic haloaryls.

Keywords: Ullmann reaction, haloaryl coupling, biaryls, polyaryls, zinc dust, ammonium formate, trialkylammonium formate

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Vladimir Bulavka