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Microwave Assisted Synthesis of Tripodal Tris(1H-1,2,3-triazol-4-yl) Cyanurates and Melamines
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1  Departamento de Química Orgánica. Facultade de Ciencias. Universidade de Santiago de Compostela. Campus Terra. 27080-Lugo. Spain

Abstract: 2,4,6-tris(prop-2-yn-1-yloxy)-1,3,5-triazine and N2,N4,N6-tri(prop-2-yn-1-yl)-1,3,5-triazine-2,4,6-triamine are used in click reactions to prepare tripodal compounds and dendrimer cores. So, 1,3-cycloaddition with benzyl azide under microwave irradiation afforded 2,4,6-tris((1-benzyl-1H-1,2,3-triazol-4-yl)methoxy)-1,3,5-triazine and N2,N4,N6-tris((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-1,3,5-triazine-2,4,6-triamine, in a 1 minute reaction with good yields.
Keywords: Triazole; triazine; tripodal; dendrimer; microwave